PowerView Get-NetGroup
Get-NetGroup -AdminCount | Get-NetGroupMember -Recurse
Enumerate groups and their members, especially those with privileges (AdminCount) and recursively.
To identify privileged groups (Domain Admins, Enterprise Admins, etc.) and list all their members. The -Recurse option gives you nested membership, which is key to understanding who has real administrative access.
If you already have BloodHound data, you don't need to do this manually. Also, if the domain is very large, recursion can be slow.